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Anions play an important role in our life, from storing our genetic code on the polyanion DNA, to being the active ingredient in agricultural fertilizers and other industrial processes. Consequently, chemists have been designing systems that can sense anionic species through a variety of methods, such as unimolecular chromophores or sensor arrays. Nonetheless, most existing sensing approaches still have some drawbacks, particularly related to obtaining adequate selectivity and achieving sensing of anions in aqueous environments. In this manuscript, we report a liquid-liquid extraction (LLE)-based sensing approach that allows the conversion of non-selective optical anion sensors that only work in organic media, into selective sensing systems that allow detection of anions in water. We tested this approach on deprotonation-based anion sensors (alizarin, naphthol AS, 4-nitrophenol, BI-Lawsone, and chromophore 1) and hydrogen bonding-based anion sensors (1,2-diaminoanthraquinone and 4-nitro-1,2-phenylenediamine). In general, the deprotonation-based sensors could be converted from a non-selective sensor for basic anions (NCO¯, H2PO4¯, AcO¯ and F¯) to a selective sensing system for NCO¯ with the aid of carefully chosen tetraalkylammonium salts as extracting agents. On the other hand, the hydrogen-bonding based sensors could be converted to a selective sensing system for the hydrophobic anion ClO4¯ using similar tetraalkylammonium salts.